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CASH-POM
Catalytic Alkane Silylation by Heterogenized Metala-Polyoxometalates
FunderFrench National Research Agency (ANR)
Funder Contribution €374,192.00
DurationFrom 01 Jan 2022
Project codeANR-21-CE07-0040
Identifiers
Description
This project proposes to explore new challenging routes for converting alkanes into alkyl silanes, products of high added-value and industrial importance. Our approach is based on a two-step sequence: a photochemical dehydrogenation of alkanes combined to the hydrosilylation of in-situ formed alkenes. To reach this objective, we will design original and stable molecular complexes based on non noble metal centers (Fe, Co) onto polyoxometalate ligands. These robust catalysts provide well-defined active sites in an unconventional coordination environment and redox-active polyoxotungstic fragments that can play the role of photocatalysts. Their heterogenization on mesoporous silicas should moreover make it possible to carry out the targeted catalytic reactions in alkane medium and thus to meet the conditions for the implementation of an original tandem catalysis designed to meet the requirements of more ecological processes and controlled energy costs for conversion of alkanes.
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This project proposes to explore new challenging routes for converting alkanes into alkyl silanes, products of high added-value and industrial importance. Our approach is based on a two-step sequence: a photochemical dehydrogenation of alkanes combined to the hydrosilylation of in-situ formed alkenes. To reach this objective, we will design original and stable molecular complexes based on non noble metal centers (Fe, Co) onto polyoxometalate ligands. These robust catalysts provide well-defined active sites in an unconventional coordination environment and redox-active polyoxotungstic fragments that can play the role of photocatalysts. Their heterogenization on mesoporous silicas should moreover make it possible to carry out the targeted catalytic reactions in alkane medium and thus to meet the conditions for the implementation of an original tandem catalysis designed to meet the requirements of more ecological processes and controlled energy costs for conversion of alkanes.
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