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CarbHydride
FunderFrench National Research Agency (ANR)
Funder Contribution €405,189.00
DurationFrom 01 Dec 2023
Project codeANR-23-CE07-0031
Open Access mandatePublications: NoResearch data: No
Identifiers
Description
As exemplified by the Stryker’s reagent, a phosphine-stabilized hexameric polymetallic copper(I) hydride [(Ph3P)CuH]6 (commercialized by Aldrich) routinely used in stoichiometric or catalytic quantities as a mild and selective reducing agent, Metal-Hydrogen (M-H) bonds occupy an important place in organic synthesis. In this project we intend develop new and original quantum-sized earth-abundant polynuclear metal–hydrides stabilized by carbene ligands for applications in chemoselective transformations of organic substrates.
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As exemplified by the Stryker’s reagent, a phosphine-stabilized hexameric polymetallic copper(I) hydride [(Ph3P)CuH]6 (commercialized by Aldrich) routinely used in stoichiometric or catalytic quantities as a mild and selective reducing agent, Metal-Hydrogen (M-H) bonds occupy an important place in organic synthesis. In this project we intend develop new and original quantum-sized earth-abundant polynuclear metal–hydrides stabilized by carbene ligands for applications in chemoselective transformations of organic substrates.
